OC 2 Peptidseminar at Universität Mainz

Flashcards and summaries for OC 2 Peptidseminar at the Universität Mainz

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Definition Tertiärstruktur

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Abspaltung Fmoc?

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Name und Struktur von EDC

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Quartärstruktur

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Was sind Hydroxy-Aminosäuren?

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Namen von Ester-Schutzgruppen

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Aminodicarbonsäuren?

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Was sind schwefelhaltige Aminosäuren?

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Definition Protein

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Was ist eine cyclische Aminosäure?

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Anforderung an Schutzgruppen

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Namen aromatischer/heteroaromatischer Aminosäuren?

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Exemplary flashcards for OC 2 Peptidseminar at the Universität Mainz on StudySmarter:

OC 2 Peptidseminar

Definition Tertiärstruktur

3D-Struktur durch weitere Faltung der Sekundärstrukturelemente

- alle weiteren intramolekularen Wechselwirkungen ausgebildet (Beeinflussung der Löslichkeit)

- Entstehung von Taschen/Hohlräumen (aktive Stellen/Substratbindestellen)

OC 2 Peptidseminar

Abspaltung Fmoc?

schwach basisch (Piperidin / DMF)

OC 2 Peptidseminar

Name und Struktur von EDC

1-Ethyl-3-(3-dimethylaminopropyl)-carbodiimid

OC 2 Peptidseminar

Quartärstruktur

räumliche Anordnung von Untereinheiten bestehend aus zwei oder mehreren Polypeptidketten

OC 2 Peptidseminar

Was sind Hydroxy-Aminosäuren?

1.) Serin (Ser)

2.) Threonin (Thr)

OC 2 Peptidseminar

Namen von Ester-Schutzgruppen

C-terminale Schutzgruppen

1.) OMe / OEt (Methanol / Ethanol)

2.) OtBu (Kalium-tertbutanolat)

3.) OAllyl (Allylbromid / NaHCO3)

4.) OBz (Benzylalkohol / H+)

OC 2 Peptidseminar

Aminodicarbonsäuren?

1.) Asparaginsäure (Asp)

2.) Glutaminsäure (Glu)

OC 2 Peptidseminar

Was sind schwefelhaltige Aminosäuren?

1.) Cystein (Cys)

2.) Methionin (Met)

OC 2 Peptidseminar

Definition Protein

hochmolekulare Polypeptide (über 100 Aminosäuren)

OC 2 Peptidseminar

Was ist eine cyclische Aminosäure?

Prolin (Pro)

OC 2 Peptidseminar

Anforderung an Schutzgruppen

1.) Stabil während Aktivierung der Carboxygruppe & Synthese der Aminbildung

2.) Leicht, unter milden Bedingungen und selektiv abspaltbar (Orthogonalität)


OC 2 Peptidseminar

Namen aromatischer/heteroaromatischer Aminosäuren?

1.) Phenylalanin (Phe)

2.) Tyrosin (Tyr)

3.) Tryptophan (Trp)

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